| Card # |
English |
English |
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| 1 |
1.Secondary carbocation 2.Hydrolysis e.g CH3CH(OH)CH3 major product+H2SO4 |
Alkenes- 1.H2SO4 2.H2O e.g CH3CH=CH2 |
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| 2 |
Acid hydrolysis e.g (CH3)2C(OH)COOH |
Ketones- acid e.g (CH3)2C(OH)CN |
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| 3 |
Acid hydrolysis e.g CH3CH(OH)COOH |
Aldehydes- acid e.g CH3CH(OH)CN |
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| 4 |
Acid hydrolysis e.g CH3CH2COOH |
Haloalkanes- heat under reflux, mineral acid e.g CH3CH2CN |
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| 5 |
Addition polymer e.g (CH3+CHCH2+)n |
Alkenes- (n-1)CH3CH=CH2 e.g CH3CHB=CH2 |
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| 6 |
Addition polymer e.g +CH2-CH2+n |
Alkenes- (n-1)CH2=CH2 e.g CH2=CH2 |
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| 7 |
Carbocation reaction/ catalytic cracking e.g C8H18(branched)+C6H12 |
Alkanes- high T(450C), zeolite catalyst e.g C14H30 |
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| 8 |
Catalytic hydrogenation e.g CH3CH2OH |
Aldehydes- H2/Ni e.g CH3CHO |
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| 9 |
Catalytic hydrogenation e.g secondary alcohol CH3CH(OH)CH3 |
Ketones- H2/Ni e.g CH3COCH3 |
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| 10 |
Complete combustion e.g 14CO2+13H2O |
Alkanes- 21 1/2O2 e.g C14H30 |
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| 11 |
Direct partial oxidation e.g H2C\O/CH2 Epoxyethane |
Alkenes- 1/2 O2, Ag catalyst e.g CH2=CH2 |
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| 12 |
E.g CH3CH(OH)CH2NH2 |
Aldehydes- H2/Ni or LiAlH4 |
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| 13 |
E.g CH3CHO |
Alcohols- K2Cr2O7/H+(aq) e.g CH3CH2OH |
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| 14 |
E.g CH3COCH3 |
Alcohols- K2Cr2O7/H+(aq) e.g CH3CH(OH)CH3 |
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| 15 |
E.g CH3COOH |
Alcohols- [O] e.g CH3CHO |
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| 16 |
Electrophilic addition e.g CH2BrCH2Br |
Alkenes- Br2 e.g CH2=CH2 |
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| 17 |
Electrophilic addition e.g CH3CH2Br |
Alkenes- HBr e.g CH2=CH2 |
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| 18 |
Electrophilic addition e.g CH3CH2OSO3H |
Alkenes- H2SO4 e.g CH2=CH2 |
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| 19 |
Electrophilic subsitution e.g C6H5COCH3 |
Acylation- C6H6/AlCl3 e.g CH3COCl acyl chloride |
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| 20 |
Electrophilic substitution e.g C6H5CH2CH3 |
Aromatic chemistry- CH2=CH2/AlCl3/HCl e.g C6H6 |
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| 21 |
Electrophilic substitution e.g C6H5COCH3 |
Aromatic chemistry- RCOCl or (RCO)2O/AlCl3 e.g C6H6 |
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| 22 |
Electrophilic substitution e.g C6H5NO2 |
Aromatic chemistry- conc. HNO3/conc.H2SO4 e.g C6H6 |
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| 23 |
Electrophilic substitution e.g C6H5R |
Aromatic chemistry- RCl/AlCl3 e.g C6H6 |
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| 24 |
Elimination e.g CH2=CH2 |
Alcohols- H2SO4 or H3PO4 e.g CH3CH2OH |
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| 25 |
Elimination e.g CH3CH=CH2 |
Haloalkanes- KOH(ethanol) e.g CH3CHBrCH3 |
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| 26 |
Elimination e.g alkene CH3CH=CH2 |
Alcohols- H2SO4 or H3PO4 e.g CH3CH(OH)CH3 |
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| 27 |
Free-radical reaction/ Thermal Cracking e.g C7H16+C3H6+2C2H4 |
Alkanes- hight p(7000kPa),T(400C-900C) e.g C14H30 |
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| 28 |
Free-radical subsitution e.g CH3Cl+HCl(+CH2Cl2 etc) |
Alkanes- Cl2 e.g CH4 |
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| 29 |
Hydrogenation e.g CH3CH3 |
Alkenes- H2/Ni e.g CH2=CH2 |
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| 30 |
Hydrolysis e.g CH3CH2OH+H2SO4 |
Alkyl hydrogensulphate- H2O e.g CH3CH2OSO3H |
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| 31 |
Hydrolysis e.g CH3COONa + alcohol ROH |
Esters- NaOH e.g CH3COOR |
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| 32 |
Nucleophilic addition e.g (CH3)2C(OH)CN |
Ketones- HCN e.g CH3COCH3 |
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| 33 |
Nucleophilic addition e.g CH3CH(OH)CN |
Aldehydes- HCN e.g CH3CHO |
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| 34 |
Nucleophilic addition e.g Secondary alcohol CH3CH(OH)CH3 |
Ketones- NaBH4 e.g CH3COCH3 |
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| 35 |
Nucleophilic addition e.g primary alcohol CH3CH2OH |
Aldehydes- NaBH4 e.g CH3CHO |
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| 36 |
Nucleophilic addition-elimination e.g CH3CONH2 |
Acylation- NH3 e.g CH3COCl acyl chlorides |
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| 37 |
Nucleophilic addition-elimination e.g CH3CONHR |
Acylation- RNH2 e.g CH3COCl acyl chloride |
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| 38 |
Nucleophilic addition-elimination e.g CH3COOCH2CH3 |
Alcohols- CH3COCl or (CH3CO)2O e.g CH3CH2OH |
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| 39 |
Nucleophilic addition-elimination e.g CH3COOH + HCl |
Acylation- H2O e.g CH3COCl acyl chloride |
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| 40 |
Nucleophilic addition-elimination e.g CH3COOR + HCl |
Acylation- ROH e.g CH3COCl acyl chloride |
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| 41 |
Nucleophilic substitution e.g CH2CH2NH2 Further reaction (CH3CH2)2NH or3N or4N+Br- |
Haloalkanes- NH3 e.g CH3CH2Br |
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| 42 |
Nucleophilic substitution e.g CH3CH2CN |
Haloalkanes- KCN(aq) e.g CH3CH2Br |
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| 43 |
Nucleophilic substitution e.g CH3CH2OH |
Haloalkanes- NaOH(aq) e.g CH3CH2Br |
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| 44 |
Nucleophilic substitution e.g secondary alcohol CH3CH(OH)CH3 |
Haloalkanes- KOH(aq) e.g CH3CHBrCH3 |
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| 45 |
Oxidation e.g CH3COOH |
Aldehydes- [O] e.g CH3CHO |
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| 46 |
Secondary carbocation e.g CH3CHBrCH3 major product |
Alkenes- HBr e.g CH3CH=CH2 |
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| 47 |
e.g (CH3)2C(OH)CH2NH2 |
Ketones- H2/Ni or LiAlH4 e.g (CH3)2C(OH)CN |
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| 48 |
e.g 2CH3COOH |
Acylation- H2O e.g (CH3CO)2O acid anhydride |
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| 49 |
e.g C6H12 |
Aromatic chemistry- H2/Ni e.g C6H6 |
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| 50 |
e.g C6H5CH=CH2 Further reaction= (CH(C6H5)CH2)n |
Aromatic chemistry- Fe2O3 e.g C6H5CH2CH3 |
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| 51 |
e.g C6H5NH2 |
Aromatic chemistry- Sn/HCl or H2/Ni e.g C6H5NO2 |
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| 52 |
e.g CH3CH2CH2NH2 |
Haloalkanes- H2/Ni or LiAlH4 e.g CH3CH2CN |
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| 53 |
e.g CH3CH2OH |
Alkenes- H2O/H3PO4 e.g CH2=CH2 |
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| 54 |
e.g CH3CONH2 + CH3COOH |
Acylation- NH3 e.g (CH3CO)2O acid anhydride |
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| 55 |
e.g CH3CONHR + CH3COOH |
Acylation- RNH2 e.g (CH3CO)2O acid anhydride |
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| 56 |
e.g CH3COOR + CH3COOH |
Acylation- ROH e.g (CH3CO)2O acid anhydride |
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| 57 |
e.g Esters CH3COONa + CO2 |
Carboxylic acids- NaHCO3 e.g CH3COOH |
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| 58 |
e.g Esters CH3COOR |
Carboxylic acids- ROH + H2SO4 e.g CH3COOH |
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| 59 |
e.g HOCH2CH2OH Ethane-1,2-diol (can be a addition polymer HO(CH2CH2O)nH)) |
Alkenes- H2O e.g CH2\O/CH2 Epoxyethane |
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| 60 |
formation of monoalkyl ethers e.g ROCH2CH2OH (Addition polymer RO(CH2CH2O)nH) |
Alkenes- ROH e.g CH2\O/CH2 Epoxyethane |
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